Since you you asked for the 'overall PSNR performance' I assumed that is what you are looking for.
Code:
aomenc.exe --help
Usage: aomenc.exe <options> -o dst_filename src_filename
Options:
--help Show usage options and exit
-c <arg>, --cfg=<arg> Config file to use
-D, --debug Debug mode (makes output deterministic)
-o <arg>, --output=<arg> Output filename
--codec=<arg> Codec to use
-p <arg>, --passes=<arg> Number of passes (1/2)
--pass=<arg> Pass to execute (1/2)
--fpf=<arg> First pass statistics file name
--limit=<arg> Stop encoding after n input frames
--skip=<arg> Skip the first n input frames
--good Use Good Quality Deadline
-q, --quiet Do not print encode progress
-v, --verbose Show encoder parameters
--psnr Show PSNR in status line
--webm Output WebM (default when WebM IO is enabled)
--ivf Output IVF
--obu Output OBU
-P, --output-partitions Makes encoder output partitions. Requires IVF output!
--q-hist=<arg> Show quantizer histogram (n-buckets)
--rate-hist=<arg> Show rate histogram (n-buckets)
--disable-warnings Disable warnings about potentially incorrect encode settings.
-y, --disable-warning-prompt Display warnings, but do not prompt user to continue.
--test-decode=<arg> Test encode/decode mismatch
off, fatal, warn
Encoder Global Options:
--yv12 Input file is YV12
--i420 Input file is I420 (default)
--i422 Input file is I422
--i444 Input file is I444
-u <arg>, --usage=<arg> Usage profile number to use
-t <arg>, --threads=<arg> Max number of threads to use
--profile=<arg> Bitstream profile number to use
-w <arg>, --width=<arg> Frame width
-h <arg>, --height=<arg> Frame height
--forced_max_frame_width Maximum frame width value to force
--forced_max_frame_height Maximum frame height value to force
--stereo-mode=<arg> Stereo 3D video format
mono, left-right, bottom-top, top-bottom, right-left
--timebase=<arg> Output timestamp precision (fractional seconds)
--fps=<arg> Stream frame rate (rate/scale)
--global-error-resilient=<a Enable global error resiliency features
-b <arg>, --bit-depth=<arg> Bit depth for codec (8 for version <=1, 10 or 12 for version 2)
8, 10, 12
--lag-in-frames=<arg> Max number of frames to lag
--large-scale-tile=<arg> Large scale tile coding (0: off (default), 1: on)
--monochrome Monochrome video (no chroma planes)
Rate Control Options:
--drop-frame=<arg> Temporal resampling threshold (buf %)
--resize-mode=<arg> Frame resize mode
--resize-denominator=<arg> Frame resize denominator
--resize-kf-denominator=<ar Frame resize keyframe denominator
--superres-mode=<arg> Frame super-resolution mode
--superres-denominator=<arg Frame super-resolution denominator
--superres-kf-denominator=< Frame super-resolution keyframe denominator
--superres-qthresh=<arg> Frame super-resolution qindex threshold
--superres-kf-qthresh=<arg> Frame super-resolution keyframe qindex threshold
--end-usage=<arg> Rate control mode
vbr, cbr, cq, q
--target-bitrate=<arg> Bitrate (kbps)
--min-q=<arg> Minimum (best) quantizer
--max-q=<arg> Maximum (worst) quantizer
--undershoot-pct=<arg> Datarate undershoot (min) target (%)
--overshoot-pct=<arg> Datarate overshoot (max) target (%)
--buf-sz=<arg> Client buffer size (ms)
--buf-initial-sz=<arg> Client initial buffer size (ms)
--buf-optimal-sz=<arg> Client optimal buffer size (ms)
Twopass Rate Control Options:
--bias-pct=<arg> CBR/VBR bias (0=CBR, 100=VBR)
--minsection-pct=<arg> GOP min bitrate (% of target)
--maxsection-pct=<arg> GOP max bitrate (% of target)
Keyframe Placement Options:
--kf-min-dist=<arg> Minimum keyframe interval (frames)
--kf-max-dist=<arg> Maximum keyframe interval (frames)
--disable-kf Disable keyframe placement
AV1 Specific Options:
--cpu-used=<arg> CPU Used (0..8)
--dev-sf=<arg> Dev Speed (0..255)
--auto-alt-ref=<arg> Enable automatic alt reference frames
--sharpness=<arg> Loop filter sharpness (0..7)
--static-thresh=<arg> Motion detection threshold
--single-tile-decoding=<arg Single tile decoding (0: off (default), 1: on)
--tile-columns=<arg> Number of tile columns to use, log2
--tile-rows=<arg> Number of tile rows to use, log2 (set to 0 while threads > 1)
--arnr-maxframes=<arg> AltRef max frames (0..15)
--arnr-strength=<arg> AltRef filter strength (0..6)
--tune=<arg> Distortion metric tuned with
psnr, ssim, cdef-dist, daala-dist
--cq-level=<arg> Constant/Constrained Quality level
--max-intra-rate=<arg> Max I-frame bitrate (pct)
--max-inter-rate=<arg> Max P-frame bitrate (pct)
--gf-cbr-boost=<arg> Boost for Golden Frame in CBR mode (pct)
--lossless=<arg> Lossless mode (0: false (default), 1: true)
--enable-cdef=<arg> Enable the constrained directional enhancement filter (0: false, 1: true (default))
--enable-restoration=<arg> Enable the loop restoration filter (0: false, 1: true (default))
--enable-qm=<arg> Enable quantisation matrices (0: false (default), 1: true)
--qm-min=<arg> Min quant matrix flatness (0..15), default is 8
--qm-max=<arg> Max quant matrix flatness (0..15), default is 15
--enable-dist-8x8=<arg> Enable dist-8x8 (0: false (default), 1: true)
--frame-parallel=<arg> Enable frame parallel decodability features (0: false (default), 1: true)
--error-resilient=<arg> Enable error resilient features (0: false (default), 1: true)
--aq-mode=<arg> Adaptive quantization mode (0: off (default), 1: variance 2: complexity, 3: cyclic refresh)
--deltaq-mode=<arg> Delta qindex mode (0: off (default), 1: deltaq 2: deltaq + deltalf)
--frame-boost=<arg> Enable frame periodic boost (0: off (default), 1: on)
--noise-sensitivity=<arg> Noise sensitivity (frames to blur)
--tune-content=<arg> Tune content type
default, screen
--cdf-update-mode=<arg> CDF update mode for entropy coding (0: no CDF update; 1: update CDF on all frames(default); 2: selectively update CDF on some frames
--color-primaries=<arg> Color primaries (CICP) of input content:
bt709, unspecified, bt601, bt470m, bt470bg, smpte240, film, bt2020, xyz, smpte431, smpte432, ebu3213
--transfer-characteristics= Transfer characteristics (CICP) of input content:
unspecified, bt709, bt470m, bt470bg, bt601, smpte240, lin, log100, log100sq10, iec61966, bt1361, srgb, bt2020-10bit, bt2020-12bit, smpte2084, hlg, smpte428
--matrix-coefficients=<arg> Matrix coefficients (CICP) of input content:
identity, bt709, unspecified, fcc73, bt470bg, bt601, smpte240, ycgco, bt2020ncl, bt2020cl, smpte2085, chromncl, chromcl, ictcp
--chroma-sample-position=<a The chroma sample position when chroma 4:2:0 is signaled:
unknown, vertical, colocated
--min-gf-interval=<arg> min gf/arf frame interval (default 0, indicating in-built behavior)
--max-gf-interval=<arg> max gf/arf frame interval (default 0, indicating in-built behavior)
--sb-size=<arg> Superblock size to use
dynamic, 64, 128
--num-tile-groups=<arg> Maximum number of tile groups, default is 1
--mtu-size=<arg> MTU size for a tile group, default is 0 (no MTU targeting), overrides maximum number of tile groups
--timing-info=<arg> Signal timing info in the bitstream:
unspecified, constant
--film-grain-test=<arg> Film grain test vectors (0: none (default), 1: test-1 2: test-2, ... 16: test-16)
--film-grain-table=<arg> Path to file containing film grain parameters
--enable-ref-frame-mvs=<arg Enable temporal mv prediction (default is 1)
-b <arg>, --bit-depth=<arg> Bit depth for codec (8 for version <=1, 10 or 12 for version 2)
8, 10, 12
--input-bit-depth=<arg> Bit depth of input
--sframe-dist=<arg> S-Frame interval (frames)
--sframe-mode=<arg> S-Frame insertion mode (1..2)
--annexb=<arg> Save as Annex-B
Stream timebase (--timebase):
The desired precision of timestamps in the output, expressed
in fractional seconds. Default is 1/1000.
Included encoders:
av1 - AOMedia Project AV1 Encoder 0.1.0-9092-gcc30cc79f (default)
Use --codec to switch to a non-default encoder.
I don't see an option for a frame by frame PSNR comparision, so you probably have to do that by yourself somehow.